Crystalline splittings of lines of35Cl NQR spectra of phosphorus acid chlorides
- 13 Downloads
A statistical analysis of the crystalline splittings of the35Cl NQR spectra in the series R1R2P(O)Cl (R1, R2=Alk, Ar, Hal) revealed that the error in correlating the frequencies with theσ-constants of the substituents is due mainly to the crystal effect.
KeywordsChloride Phosphorus Acid Chloride Phosphorus Acid Crystal Effect
- 1.G. K. Semin, T. A. Babushkina, and G. G. Yakobson, Application of Nuclear Quadrupole Resonance in Chemistry [in Russian], “Khimiya” (1972), p. 100.Google Scholar
- 2.G. K. Semin and E. V. Bryukhova, Chem. Commun.,1968, 605.Google Scholar
- 3.A. D. Brodskii and V. L. Kan, Concise Handbook on Mathematical Processing of Observation Results [in Russian], Standartgiz (1960), p. 84.Google Scholar
- 4.T. A. Babushkina, V. I. Robas, and G. K. Semin, in monograph “Radiospectroscopy of Solids” [in Russian], Atomizdat (1967), p. 221.Google Scholar