Conclusions
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1.
When the Meerwein ester and the dimethyl ester of bicyclo[3.3.1]nonane-2,6-dione-3,7-dicar-boxylic acid are brominated in bromine medium the ester groups are replaced by halogen atoms.
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2.
Together with the mono- and dibromo derivatives of the bicyclo[3.3.1]nonane, a compound with the noradamantane structure is formed when the Meerwein ester is brominated in a solvent in the light.
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Literature cited
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S. V. Rogozina, Dissertation [in Russian], Moscow (1972).
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H. Meerwein, F. Kiel, and C. Klösgen, J. Prakt. Chem.,104, 161 (1922).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2765–2767, December, 1974.
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Zavarzin, I.V., Klimova, T.A., Krayushkin, M.M. et al. α-Bromo ketones of bicyclo [3.3.1]nonane series communication 1. Russ Chem Bull 23, 2668–2670 (1974). https://doi.org/10.1007/BF00923702
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DOI: https://doi.org/10.1007/BF00923702