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α-Bromo ketones of bicyclo [3.3.1]nonane series communication 1

Bromination of meerwein ester and of dimethyl ester of bicyclo[3.3.1]nonane-2, 6-dione-3, 7-dicarboxylic acid

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When the Meerwein ester and the dimethyl ester of bicyclo[3.3.1]nonane-2,6-dione-3,7-dicar-boxylic acid are brominated in bromine medium the ester groups are replaced by halogen atoms.

  2. 2.

    Together with the mono- and dibromo derivatives of the bicyclo[3.3.1]nonane, a compound with the noradamantane structure is formed when the Meerwein ester is brominated in a solvent in the light.

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Literature cited

  1. V. D. Sukhoverkhov, Dissertation [in Russian], Kiev (1969).

  2. S. V. Rogozina, Dissertation [in Russian], Moscow (1972).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. V. Zavarzin, T. A. Klimova, M. M. Krayushkin, V. V. Sevost'yanova & S. S. Novikov

Authors
  1. I. V. Zavarzin
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  2. T. A. Klimova
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  3. M. M. Krayushkin
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  4. V. V. Sevost'yanova
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  5. S. S. Novikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2765–2767, December, 1974.

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Zavarzin, I.V., Klimova, T.A., Krayushkin, M.M. et al. α-Bromo ketones of bicyclo [3.3.1]nonane series communication 1. Russ Chem Bull 23, 2668–2670 (1974). https://doi.org/10.1007/BF00923702

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  • DOI: https://doi.org/10.1007/BF00923702

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