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Reduction of β-dicarbonyl compounds with sodium borohydride

  • N. K. Levchenko
  • G. M. Segal'
  • I. V. Torgov
Organic and Biological Chemistry

Conclusions

The reduction of the monoethylene ketals of cyclicβ-diketones and the enol acetates ofβ-diketones with sodium borohydride is stereospecific, but proceeds with the formation of different isomers of the hydroxy ketals.

Keywords

Sodium Acetate Enol Borohydride Sodium Borohydride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    W. F. Gannon and H. O. House, Organic Syntheses,40, 14 (1960).Google Scholar
  2. 2.
    D. J. Cram and K. B. Koecky, J. Am. Chem. Soc.,81, 2748 (1959).Google Scholar
  3. 3.
    L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963), p. 137.Google Scholar
  4. 4.
    E. Buchta and H. Bayer, Ann. Chem.,573, 227 (1951).Google Scholar
  5. 5.
    J. Pascual and J. Castells, J. Am. Chem. Soc.,74, 2899 (1952).Google Scholar
  6. 6.
    G. V. Kondrat'eva, G. A. Kogan, T. M. Fadeeva, and S. I. Zav'yalov, Izv. Akad. Nauk SSSR, Ser. Khim.,1964, 1648.Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • N. K. Levchenko
    • 1
  • G. M. Segal'
    • 1
  • I. V. Torgov
    • 1
  1. 1.M. M. Shemyakin Institute of the Chemistry of Natural CompoundsAcademy of Sciences of the USSRMoscow

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