The structure of organophosphorus compounds 7. The crystalline and molecular structures of dimethylammonium O, O'-diisopropyldithiophosphate [NMe2H2]+[(i-PrO)2PS2]

  • A. E. Kalinin
  • V. G. Andrianov
  • Yu. T. Struchkov
Physical Chemistry


  1. 1.

    Dimethylammonium O. O'-diisopropyldithiophosphate [NMe2H2]+[(i-PrO)2PS2] (I) is composed of anions and cations joined into an infinite chain parallel to the c axis by hydrogen bonds of the N-H...S type.

  2. 2.

    Comparison showed identity of bond lengths and certain differences in the SPS, OPO, and POC valence angles in the compounds covered by this work and in potassium O,O'-dimethyl and O,O'-dibenzyldithiophosphates.



Hydrogen Potassium Hydrogen Bond Dimethyl Molecular Structure 
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Literature cited

  1. 1.
    M. Yu. Antipin, A. E. Kalinin, Yu. T. Struchkov, M. M. Aladzheva, T. A. Mastryukova, and M. I. Kabachnik, Zh. Strukt. Khim.,19, 319 (1978).Google Scholar
  2. 2.
    P. Coppens, C. H. McGillavry, S. G. Hovenkamp, and H. Douwes, Acta Crystallogr.,15, 765 (1962).Google Scholar
  3. 3.
    J. P. Hazel and R. L. Collin, Acta Crystallogr.,B28, 2279 (1972).Google Scholar
  4. 4.
    L. Giarda, F. Garbassi, and M. Calcaterra, Acta Crystallogr.,B29, 1826 (1973).Google Scholar
  5. 5.
    V. I. Andrianov, Z. Sh. Safine, and B. L. Tarnopol'skii, Zh. Strukt. Khim.,12, 1052 (1971).Google Scholar
  6. 6.
    A. N. Chekhlov, Yu. T. Struchkov, and A. I. Kitaigorodskii, Zh. Strukt. Khim.,15, 917 (1974).Google Scholar
  7. 7.
    W. C. Hamilton and J. A. Ibers, Hydrogen Bonding in Solids, New York (1968).Google Scholar
  8. 8.
    D. Mootz and H. Wunerlich, Acta Crystallogr.,B26, 1826 (1970).Google Scholar
  9. 9.
    A. Khan Aijaz, J. P. Roux, and W. J. James, Acta Crystallogr.,B28, 2065 (1972).Google Scholar
  10. 10.
    Tables of Interatomic Distances and Configurations in Molecules and Ions. Supplement 1956–1959, Special Publication No. 18, Chemical Society, London (1965).Google Scholar
  11. 11.
    S. L. Lawton, Inorg. Chem.,9, 2269 (1970).Google Scholar
  12. 12.
    V. V. Tkachev, L. O. Atovmyan, and S. A. Shchepinov, Zh. Strukt. Khim.,17, 945 (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. E. Kalinin
    • 1
  • V. G. Andrianov
    • 1
  • Yu. T. Struchkov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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