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The structure of organophosphorus compounds 7. The crystalline and molecular structures of dimethylammonium O, O'-diisopropyldithiophosphate [NMe2H2]+[(i-PrO)2PS2]

  • A. E. Kalinin
  • V. G. Andrianov
  • Yu. T. Struchkov
Physical Chemistry

Conclusions

  1. 1.

    Dimethylammonium O. O'-diisopropyldithiophosphate [NMe2H2]+[(i-PrO)2PS2] (I) is composed of anions and cations joined into an infinite chain parallel to the c axis by hydrogen bonds of the N-H...S type.

     
  2. 2.

    Comparison showed identity of bond lengths and certain differences in the SPS, OPO, and POC valence angles in the compounds covered by this work and in potassium O,O'-dimethyl and O,O'-dibenzyldithiophosphates.

     

Keywords

Hydrogen Potassium Hydrogen Bond Dimethyl Molecular Structure 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. E. Kalinin
    • 1
  • V. G. Andrianov
    • 1
  • Yu. T. Struchkov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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