Advertisement

Nitration of mononitrocarbanions, nitroform, and halodinitromethanes with nitroxyl fluoride

  • B. S. Fedorov
  • R. G. Gafurov
  • L. T. Eremenko
Brief Communications
  • 18 Downloads

Conclusions

  1. 1.

    gem-Dinitroalkanes are formed when mononitroalkane salts are nitrated with nitroxyl fluoride.

     
  2. 2.

    In contrast to the gem-dinitroalkanes, nitroform, and the halodinitromethanes can be nitrated with nitroxyl fluoride without prior conversion to the salt.

     

Keywords

Nitrate Fluoride Nitration Nitroxyl Nitroform 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    R. G. Gafurov, B. S. Fedorov, and L. T. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1594 (1971).Google Scholar
  2. 2.
    R. B. Kaplan and H. Schechter, J. Am. Chem. Soc.,83, 3535 (1961).Google Scholar
  3. 3.
    S. S. Novikov, O. V. Lebedev, L. I. Khmel'nitskii, and Yu. P. Egorov, Zh. Obshch. Khim.,28, 2305 (1958).Google Scholar
  4. 4.
    Chemistry Handbook [in Russian], Vol. 2, Goskhimizdat, Moscow (1963).Google Scholar
  5. 5.
    A. V. Ershova, V. N. Gogitidze, V. M. Belikov, and S. S. Novikov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 943 (1959).Google Scholar
  6. 6.
    A. Meyer, Ann. Chem.,175, 114 (1875).Google Scholar
  7. 7.
    L. T. Eremenko and F. Ya. Natsibullin, Izv. Akad. Nauk SSSR, Ser. Khim., 676 (1968).Google Scholar
  8. 8.
    E. Schmidt, R. Schumacher, and H. Kuhlman, Ber.,54, 1483 (1921).Google Scholar
  9. 9.
    R. E. Olsen, D. V. Fish, and E. E. Khamel, Contemporary Chemistry of Rocket Fuel [in Russian], Atomizdat, Moscow (1972).Google Scholar
  10. 10.
    V. I. Slovetskii, A. I. Ivanov, S. A. Shevelev, A. A. Fainzil'berg, and S. S. Novikov, Zh. Fiz. Khim.,41, 834 (1967).Google Scholar
  11. 11.
    V. I. Slovetskii, L. V. Okhlobystina, A. A. Fainzil'berg, A. I. Ivanov, L. I. Biryukova, and S. S. Novikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2063 (1965).Google Scholar
  12. 12.
    H. F. Adolph and M. J. Kamlet, J. Am. Chem. Soc.,88, 4761 (1966).Google Scholar
  13. 13.
    T. N. Hall, J. Org. Chem.,29, 3587 (1964).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • B. S. Fedorov
    • 1
  • R. G. Gafurov
    • 1
  • L. T. Eremenko
    • 1
  1. 1.Division of Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

Personalised recommendations