Synthesis of triorganylchlorosilanes by catalytic reaction of triorganylsilanes with chlorobenzene

  • Yu. I. Khudobin
  • N. A. Andreeva
  • N. P. Kharitonov
  • M. G. Voronkov
Organic and Biological Chemistry
  • 24 Downloads

Conclusions

A study was made of the reaction for replacing the hydrogen atom, attached to the silicon in triorganylsilanes, by the chlorine atom when reaction is with chlorobenzene in the presence of colloidal nickel as the catalyst. A probable scheme of the reaction mechanism is given.

Keywords

Hydrogen Silicon Nickel Chlorine Hydrogen Atom 

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Literature cited

  1. 1.
    Yu. I. Khudobin, B. N. Dolgov, and N. P. Kharitonov, in: Chemistry and Practical Application of Organosilicon Compounds [in Russian], Izd. AN SSSR (1961), No. 6, p. 155.Google Scholar
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    Yu. I. Khudobin, M. G. Voronkov, and N. P. Kharitonov, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 598 (1967).Google Scholar
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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • Yu. I. Khudobin
    • 1
    • 2
  • N. A. Andreeva
    • 1
    • 2
  • N. P. Kharitonov
    • 1
    • 2
  • M. G. Voronkov
    • 1
    • 2
  1. 1.I. V. Grebenshchikov Institute of Silicate ChemistryAcademy of Sciences of the USSRLeningrad
  2. 2.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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