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Reaction of 2,6-di-tert-butyl-1,4-benzoquinone diazide with diazoalkanes

  • G. F. Bannikov
  • M. G. Luchinskaya
  • G. A. Nikiforov
  • V. V. Ershov
Organic Chemistry
  • 27 Downloads

Conclusions

  1. 1.

    The reaction of 2,6-di-tert-butyl-1,4-benzoquinonediazide with diazoalkanes leads to the corresponding azines or N-aminoaziridine hydrazones, the reaction products of azines with dialkanes.

     
  2. 2.

    The route described for forming the N-aminoaziridine derivatives can serve as a preparative method for their synthesis.

     

Keywords

Benzoquinone Hydrazones Azine Preparative Method Diazide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    O. P. Studzinskii and I. K. Korobitsina, Usp. Khim.,39, 1754 (1970).Google Scholar
  2. 2.
    P. Schuster and O. Palansky, Monatsh. Chem.,96, 396 (1965).Google Scholar
  3. 3.
    R. Huisgen and R. Fleischmann, Liebigs Ann. Chem.,623, 47 (1959).Google Scholar
  4. 4.
    S. A. Giller, A. V. Eremeev, M. Yu. Lidak, É. É. Liepin'sh, and I. Ya. Kalviln'sh, Khim. Geterotsikl. Soedin.,1971, 2144.Google Scholar
  5. 5.
    V. V. Ershov, G. N. Bogdanov, and A. A. Volod'kin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1963, 157.Google Scholar
  6. 6.
    G. M. Coppinger, Tetrahedron,18, 61 (1962).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • G. F. Bannikov
    • 1
  • M. G. Luchinskaya
    • 1
  • G. A. Nikiforov
    • 1
  • V. V. Ershov
    • 1
  1. 1.Institute of Chemical-PhysicAcademy of Sciences of the USSRMoscow

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