Conclusions
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1.
The alkenyl carbonium ions that are formed on the surface of H-mordenite when alkylbenzenes are alkylated with propylene are secondary products, and do not take part in the alkylation reaction.
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2.
The alkylation reaction and the hydrogen redistribution can proceed with the involvement of the same alkyl carbonium ions.
Literature cited
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H. P. Leftin, Carbonium Ions, Vol. 1, New York (1968), p. 353.
T. Tashibana and M. Okuda, Bull. Chem. Soc. Japan,36, 462 (1963).
G. A. Olah, C. U. Pittman, Jr., and M. C. R. Symons, Carbonium Ions, Vol. 1, New York (1968), p. 153.
F. E. Shephard, J. J. Rooney, and C. Kemball, J. Catalysis,1, 379 (1962).
N. C. Deno, Carbonium Ions, Vol. 2, New York (1970), p. 801.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1887–1890, August, 1974.
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Andreev, V.M., Kazanskii, V.B. Reactivity of alkenyl carbonium ions, formed on surface of H-mordenite during alkylation of alkylbenzenes with propylene. Russ Chem Bull 23, 1811–1813 (1974). https://doi.org/10.1007/BF00923220
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DOI: https://doi.org/10.1007/BF00923220