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Telomerization of ethylene with acetonitrile and capronitrile

  • A. B. Terent'ev
  • M. A. Churilova
  • V. I. Dostovalova
  • V. A. Svoren'
Organic and Biological Chemistry
  • 17 Downloads

Conclusions

  1. 1.

    The telomerization of ethylene with acetonitrile and capronitrile goes with a rearrangement of the radicals and a 1,5 migration of the hydrogen atom.

     
  2. 2.

    A measurement of the partial chain transfer constants and the relative isomerization constant in the telomerization of ethylene with acetonitrile revealed that the rearrangement goes to less degree in the given reaction than in the reactions of ethylene with methyl acetate, propionitrile, and methyl propionate.

     

Keywords

Hydrogen Methyl Acetate Ethylene Migration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • A. B. Terent'ev
    • 1
  • M. A. Churilova
    • 1
  • V. I. Dostovalova
    • 1
  • V. A. Svoren'
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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