Conclusions
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1.
Under the optimum conditions the main direction of the oxidative dehydrogenation of n-hexane in the presence of hydrochloric acid and iron oxide, deposited on silica gel containing CsCl, is the formation of n-hexenes, the yield of which reaches 22–23% when based on hexane passed through, or 38% when based on reacted hexane.
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2.
n-Hexenes, with the same ratio of the isomers as in the oxidative dehydrogenation of n-hexane with hydrochloric acid, are formed from 1-chlorohexane on the same catalyst in an air stream, at 400°, and a chloride space velocity of 1 h−1.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1811–1813, August, 1974.
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Tarasova, G.A., Roitberg, S.Y. Oxidative dehydrogenation of n-hexane in presence of hydrochloric acid. Russ Chem Bull 23, 1729–1731 (1974). https://doi.org/10.1007/BF00923198
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DOI: https://doi.org/10.1007/BF00923198