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Low-temperature conjugated oxidation of saturated hydrocarbons involving salts of variable valence metals

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A number of simple and comparatively efficient systems was proposed for the oxidation of saturated hydrocarbons in conjugation with the oxidation of a number of metal salts of variable valence, in which connection nearly 100% selectivity in product (either ketone or alcohol) can be achieved in these systems.

  2. 2.

    A study was made of the effect of the individual components of the system on the yield of oxidation products and on the selectivity.

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Authors and Affiliations

  1. Division of Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    E. I. Karasevich, N. Z. Muradov & A. A. Shteinman

Authors
  1. E. I. Karasevich
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  2. N. Z. Muradov
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  3. A. A. Shteinman
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1805–1811, August, 1974.

We wish to thank A. E. Shilov for taking part in a discussion of the results.

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Karasevich, E.I., Muradov, N.Z. & Shteinman, A.A. Low-temperature conjugated oxidation of saturated hydrocarbons involving salts of variable valence metals. Russ Chem Bull 23, 1724–1728 (1974). https://doi.org/10.1007/BF00923197

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  • DOI: https://doi.org/10.1007/BF00923197

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