Skip to main content
SpringerLink
Log in

Thermochemistry of N-nitro- and N -nitrosoamines of the alicyclic series

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The thermochemical characteristics of N,N-dinitropiperazine and N,N-dinitrosopiperazine were determined. The enthalpy of sublimation of hexahydro-l,3,5-trinitrosotriazine was determined.

  2. 2.

    The difference in the thermochemical principles of aliphatic and alicyclic N-nitro-N-nitrosoamines is due to the interaction of the functional groups in the ring.

  3. 3.

    The cleavage energies of the nitrogen-oxygen bond in N-nitropiperazine, N,N-dinitropiperazine, and hexahydro-l,3,5-trinitrotriazine were calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. R. Cass, S. E. Fletcher, C. T. Mortimer, P. G. Quincey, and H. D. Springall, J. Chem. Soc., 958 (1958).

  2. B. L. Korsunskii, V. I. Pepekin, Yu. A. Lebedev, and A. Ya. Apin, Izv. Akad. Nauk SSSR, Ser. Khim., 525 (1967).

  3. V. I. Pepekin, R. G. Gafurov, Yu. A. Lebedev, L. T. Eremenko, E. M. Sogomonyan, and A. Ya. Apin, Izv. Akad. Nauk SSSR, Sogomonyan, and A. Ya. Ser. Khim., 318 (1973).

  4. E. E. Baroody and G. A. Carpenter, J. Chem. Engng. Data,18, No. 1, 28 (1973).

    Google Scholar 

  5. Yu. N. Matyushin, I. B. V'yunova, V. I. Pepekin, and A. Ya. Apin, Izv. Akad. Nauk SSSR, Ser. Khim., 2443 (1971).

  6. I. V. Hamilton and T. F. Fagley, J. Chem. Engng. Data,13, No. 4, 523 (1968).

    Google Scholar 

  7. O. F. Golovanova, V. I. Pepekin, B. L. Korsunskii, L. T. Eremenko, R. G. Gafurov, and F. I. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1495 (1974).

  8. D. Stahl, W. Westram, and G. Zinke, Chemical Thermodynamics of Organic Compounds [Russian translation], Mir (1971).

  9. I. M. Rosen and C. Diskinson, J. Chem. Engng. Data,14, No. 1, 20 (1969).

    Google Scholar 

  10. V. I. Vedeneev, L. V. Gurvich, V. N. Kondrat'ev, V. A. Medvedev, and E. D. Frankevich, Cleavage Energies of Chemical Bonds. Ionization Potentials and Electron Affinity [in Russian], Izd. AN SSSR (1962).

  11. B. L. Korsunskii, F. I. Dubovitskii, and E. A. Shurygin, Izv. Akad. Nauk SSSR, Ser. Khim., 452 (1967).

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. I. Pepekin, Yu. N. Matyushin & Yu. A. Lebedev

Authors
  1. V. I. Pepekin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. N. Matyushin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Lebedev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1786–1790, August, 1974.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pepekin, V.I., Matyushin, Y.N. & Lebedev, Y.A. Thermochemistry of N-nitro- and N -nitrosoamines of the alicyclic series. Russ Chem Bull 23, 1707–1710 (1974). https://doi.org/10.1007/BF00923193

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00923193

Keywords

Search

Navigation