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Method of determination of the reactivity of diphenylnitrogen radicals in processes of stripping of a hydrogen atom

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In an inert solvent (p-xylene) at 70°, the decomposition of tetraphenylhydrazine into diphenylnitrogen radicals occurs as a reversible reaction with a low value of the equilibrium constant and is not complicated by disproportionation of the Ph2N' radicals.

  2. 2.

    Using arylhydrazines as the source of diarylnitrogen radicals, a method was proposed for the determination of the reactivity of these radicals in reactions of stripping of hydrogen.

  3. 3.

    The ratios of the constants kHX/√k9 were determined by the reaction of diphenylnitrogen radicals with various hydrogen donors.

  4. 4.

    The rate constant of the reaction of diphenylnitrogen with cumyl hydroperoxide was measured.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    M. Ya. Meskina, G. V. Karpukhina & Z. K. Maizus

Authors
  1. M. Ya. Meskina
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  2. G. V. Karpukhina
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  3. Z. K. Maizus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1755–1761, August, 1974.

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Meskina, M.Y., Karpukhina, G.V. & Maizus, Z.K. Method of determination of the reactivity of diphenylnitrogen radicals in processes of stripping of a hydrogen atom. Russ Chem Bull 23, 1675–1680 (1974). https://doi.org/10.1007/BF00923186

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  • DOI: https://doi.org/10.1007/BF00923186

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