IR spectra of complexes of HCl and HBr with olefins at low temperatures

  • Ya. M. Kimel'fel'd
  • É. V. Lumer
  • A. P. Shvedchikov
Physical Chemistry


  1. 1.

    At low temperatures HCl and HBr form molecular complexes with olefins, and as the number of-alkyl substituents at the C =C bond increases, the basic properties of the olefins increase sharply.

  2. 2.

    In the system hydrohalide-olefin, a significant role is played by the forces of charge transfer.



Significant Role Charge Transfer Basic Property Molecular Complex Bond Increase 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    G. B. Sergeev, in: Modern Problems of Physical Chemistry [in Russian], Izd. Mosk. Un-ta,4, 20 (1970).Google Scholar
  2. 2.
    V. I. Gol'danskii, A. P. Shvedchikov, A. M. Kaplan, and I. M. Barkalov, Dokl. Akad. Nauk SSSR,195, 394 (1970).Google Scholar
  3. 3.
    Ya. M. Kimel'fel'd, A. B. Mostovoi, and L. I. Fainshtein, Dokl. Akad. Nauk SSSR,209, 105 (1973).Google Scholar
  4. 4.
    C. Girardet, D. Robert, and L. Galstry, J. Chem. Phys.,55, 5304 (1971).Google Scholar
  5. 5.
    Ya. M. Kimel'fel'd, E. V. Lumer, and A. P. Shvedchikov, Izv. Akad. Nauk SSSR, Ser. Khim., 979 (1973).Google Scholar
  6. 6.
    A. J. Barnes, H. E. Hallam, and G. F. Scrimshaw, Trans. Faraday Soc.,65, 3150, 3159, 3172 (1969).Google Scholar
  7. 7.
    L. M. Sverdlov, M. A. Kovner, and E. P. Krainov, Vibrational Spectra of Polyatomic Molecules [in Russian], Nauka (1970), p. 234.Google Scholar
  8. 8.
    A. V. Iogansen, G. A. Kurkchi, and O. V. Levina, Zh. Prikl. Spektr.,18, 676 (1973).Google Scholar
  9. 9.
    A. J. Barnes, J. B. Darves, H. E. Hallam, and J. D. R. Howells, J. Chem. Soc. Faraday Trans.,II, 246 (1973).Google Scholar
  10. 10.
    J. E. Bertie and D. J. Millen, J. Chem. Soc., 497 (1965).Google Scholar
  11. 11.
    R. M. Seel and N. Sheppard, Spectrochim. Acta,A 25, 1287 (1969).Google Scholar
  12. 12.
    H. Ratajczak, J. Phys. Chem.,76, 3000 (1972).Google Scholar
  13. 13.
    H. Ratajczak, J. Phys. Chem.,76, 3991 (1972).Google Scholar
  14. 14.
    R. S. Mulliken and W. B. Person, Molecular Complexes, Wiley-Interscience, New York (1969), p. 59.Google Scholar
  15. 15.
    H. Ratajczak, Z. Mielke, and W. J. Orville-Thomas, J. Molec. Structure,14, 165 (1972).Google Scholar
  16. 16.
    Ya. M. Kimel'fel'd, E. V. Lumer, and A. P. Shvedchikov, Dokl. Akad. Nauk SSSR,214, 142 (1974).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • Ya. M. Kimel'fel'd
    • 1
    • 2
  • É. V. Lumer
    • 1
    • 2
  • A. P. Shvedchikov
    • 1
    • 2
  1. 1.Institute of SpectroscopyAcademy of Sciences of the USSRMoscow
  2. 2.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

Personalised recommendations