Conclusions
-
1.
The IR spectra of solidβ-hydroxyethyliminodiacetic acid (H2X), its acid (KHX) and neutral (K2X) potassium salts, as well as their deutero-derivatives, were studied.
-
2.
From an analysis of the vibration frequencies of the C-O, C-N, C-H, and N-H bonds, a betaine structure of H2X and its acid potassium salt follows.
-
3.
The values of the vibration frequencies of the alcohol O-H bond in the IR spectra of H2X and KHX indicate the participation of a hydroxyl group in the formation of hydrogen bonds.
Similar content being viewed by others
Literature cited
V. P. Khramov and G. A. Aliev, Zh. Neorgan. Khimii,17, 1845 (1970).
N. M. Prutkova, L. I. Martynenko, A. I. Grigor'ev, and N. D. Mitrofanova, Zh. Neorgan. Khimii,12, 126 (1967).
A. I. Grigor'ev, N. D. Mitrofanova, and L. I. Martynenko, Zh. Neorgan. Khimii,10, 1409 (1965).
L. I. Martynenko, N. I. Pechurova, A. I. Grigor'ev, and V. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 1236 (1970).
A. Novac, M. Cotreit, and J. Joussof-Dubien, Bull. Soc. Chim. France, 1808 (1965).
A. Novac, M. Cotreit, J. Joussof-Dubien, and J. Lascomb, Inorgan. Chem.,4, 767 (1967).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], IL (1966).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1706–1710, August, 1974.
Rights and permissions
About this article
Cite this article
Filippova, É.D., Mitrofanova, N.D., Martynenko, L.I. et al. IR spectroscopic investigation of solid β-hydroxyethyliminodiacetic acid and its potassium salt. Russ Chem Bull 23, 1630–1633 (1974). https://doi.org/10.1007/BF00923177
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00923177