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Isomerization of cis-dichlorodiammine platinum (II) in aqueous solution

  • Yu. G. Breusova-Baidala
  • N. N. Zheligovskaya
  • V. I. Spitsyn
Inorganic Chemistry

Conclusions

  1. 1.

    The UV spectra of aqueous solutions of cis- and trans-dichlorodiammine complexes of Pt(II) were measured, and the possibility of using UV spectroscopy for the identification of these isomeric compounds was demonstrated.

     
  2. 2.

    The isomerization of cis-dichlorodiammineplatinum (II) to the trans-form, proceeding spontaneously in aqueous solution, was demonstrated UV and IR spectroscopically.

     

Keywords

Spectroscopy Aqueous Solution Platinum Isomeric Compound 
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Literature cited

  1. 1.
    A. V. Nikolaev, Dokl. Akad. Nauk SSSR,20, 577 (1938).Google Scholar
  2. 2.
    A. V. Nikolaev and A. M. Rubinshtein, Izv. Sektora Platiny. IONKh AN SSSR, No. 1, 125 (1948).Google Scholar
  3. 3.
    A. A. Grinberg and M. I. Gel'fman, Dokl. Akad. Nauk SSSR,149, 1328 (1963).Google Scholar
  4. 4.
    Yu. G. Breusova, Abstracts of Reports at the Scientific Conference of Young Scientists at Moscow State University [in Russian], Izd. Mosk. Un-ta (1968).Google Scholar
  5. 5.
    Yu. G. Breusova, N. N. Zheligovskaya, and V. I. Spitsyn, Summaries of Reports at the 10th All-Union Conference on the Chemistry of Complex Compounds [in Russian], Naukova Dumka, Kiev (1969).Google Scholar
  6. 6.
    A. A. Grinberg, M. I. Gel′fman, and S. I. Pechenyuk, Zh. Neorgan. Khim.,15, 487 (1970).Google Scholar
  7. 7.
    I. I. Chernyaev (editor), The Synthesis of Complex Compounds of Metals of the Platinum Group [in Russian], Nauka (1964).Google Scholar
  8. 8.
    A. V. Babaeva, Dokl. Akad. Nauk SSSR,20, 365 (1938).Google Scholar
  9. 9.
    A. V. Babaeva, Dokl. Akad. Nauk SSSR,40, 167 (1943).Google Scholar
  10. 10.
    A. V. Babaeva and M. A. Mosyagina, Izv. Akad. Nauk SSSR, Otd. Khim., 227 (1953).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • Yu. G. Breusova-Baidala
    • 1
  • N. N. Zheligovskaya
    • 1
  • V. I. Spitsyn
    • 1
  1. 1.Lomonosov Moscow State UniversityUSSR

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