Conclusions
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1.
Some substituted π-allyl-π-cyclopentadienylrhodium chlorides were synthesized by the simultaneous allylation-cyclopentadienylation of rhodium trichloride using allylmercury halides and thallium cyclopentadienide.
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2.
The replacement of the chlorine in π-allyl-π-cyclopentadienylrhodium chloride by other anionic ligands was studied.
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Literature cited
J. Powel and B. L. Shaw, J. Chem. Soc., A, 583 (1968).
A. Z. Rubezhov, A. S. Ivanov, and S. P. Gubin, Izv. Akad. Nauk SSSR, Ser. Khim., 951 (1973).
A. N. Nesmeyanov, R. B. Materikova, and N. S. Kochetkova, Izv. Akad. Nauk SSSR, Ser. Khim., 1334 (1963).
W. Kitching, T. Sakakiyama, Z. Rappoport, P. D. Sleezer, S. Winstein, and W. G. Young, J. Am. Chem. Soc.,94, 2329 (1972).
A. Z. Rubezhov, L. I. Voronchikhina, and S. P. Gubin, Izv. Akad. Nauk SSSR, Ser. Khim., 2116 (1972).
A. N. Nesmeyanov and R. A. Sokolik, Methods in Heteroorganic Chemistry, Boron, Aluminum, Gallium, Indium, and Thallium [in Russian], “Nauka” (1964), p. 446.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1196–1198, May, 1975.
The authors express their gratitude to L. A. Leites for discussing the IR spectra.
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Rubezhov, A.Z., Ivanov, A.S. & Gubin, S.P. New method for preparation of π-allyl-π-cyclopentadienyl compounds of rhodium. Russ Chem Bull 24, 1103–1105 (1975). https://doi.org/10.1007/BF00922978
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DOI: https://doi.org/10.1007/BF00922978