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Systems: Aluminum iodide-alkali metal iodides-nonaqueous solvent at 25°C

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The solubility isotherms of AlI3-MI-Et2O, where M=Na, K, Rb, Cs, at 25° have three crystallization branches: AlI3-Et2O, MAlI4, and MI. Similar to the other halides, aluminum iodide forms the complex AlI3·Et2O. with diethyl ether.

  2. 2.

    The equilibrium in the systems: AlI3-MI-C7H8, where M=Na, K, Rb, at 25° is determined by the successive crystallization of AlI3, MalI4, and MI. The crystallization branch of CsAl2I7 was found on the AlI3-CsI-C7H8 isotherm at 25°.

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Literature cited

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Mikheeva, S. M. Arkhipov & A. E. Pruntsev

Authors
  1. V. I. Mikheeva
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  2. S. M. Arkhipov
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  3. A. E. Pruntsev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1194–1195, May, 1975.

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Mikheeva, V.I., Arkhipov, S.M. & Pruntsev, A.E. Systems: Aluminum iodide-alkali metal iodides-nonaqueous solvent at 25°C. Russ Chem Bull 24, 1101–1102 (1975). https://doi.org/10.1007/BF00922977

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  • DOI: https://doi.org/10.1007/BF00922977

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