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Violenes as intermediate transformation products of diarylamines in oxidation of polymers

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In the initiated oxidation of polymers (polyethylene and polypropylene) the diarylamines Ar2NH are converted to the cation-radicals\(Ar_2 N\mathop N\limits_.^ + Ar_2 \) (violenes), whereas only the nitroxy radicals Ar2NO are formed when hydrocarbons are oxidized under analogous conditions.

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Authors and Affiliations

  1. Division of Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    A. P. Griva, I. R. Akhunov & E. T. Denisov

Authors
  1. A. P. Griva
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  2. I. R. Akhunov
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  3. E. T. Denisov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1190–1193, May, 1975.

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Griva, A.P., Akhunov, I.R. & Denisov, E.T. Violenes as intermediate transformation products of diarylamines in oxidation of polymers. Russ Chem Bull 24, 1097–1100 (1975). https://doi.org/10.1007/BF00922976

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  • DOI: https://doi.org/10.1007/BF00922976

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