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Hydration of unsymmetrical acetylenic γ-glycols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Based on the NMR spectral data, secondary-tertiary acetylenic γ-glycols add water under the influence of mercuric sulfate to give the 2-methyl-5,5-dialkyl-4- and 2-methyl-5, 5-dialkyl-3-tetrahydrofuranones in a 1∶1 ratio.

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Literature cited

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    A. S. Medvedeva, L. P. Safronova, I. D. Kalikhman & V. M. Vlasov

  2. Yaroslavl Pedagogic Institute, USSR

    A. S. Medvedeva, L. P. Safronova, I. D. Kalikhman & V. M. Vlasov

Authors
  1. A. S. Medvedeva
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  2. L. P. Safronova
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  3. I. D. Kalikhman
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  4. V. M. Vlasov
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1175–1178, May, 1975.

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Medvedeva, A.S., Safronova, L.P., Kalikhman, I.D. et al. Hydration of unsymmetrical acetylenic γ-glycols. Russ Chem Bull 24, 1082–1084 (1975). https://doi.org/10.1007/BF00922970

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  • DOI: https://doi.org/10.1007/BF00922970

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