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Exchange of fluorine by chlorine in perfluoroisobutylene

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Treatment of perfluoroisobutylene with various halides resulted in the exchange of fluoride for chlorine.

  2. 2.

    A method was developed for the synthesis of the monochloro- and monobromoperfluoroisobutylenes.

  3. 3.

    Substitution of chlorine for fluorine at the multiple bond of perfluoroisobutylene lowers the reactivity of the fluoroolefin toward nucleophilic reagents.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. V. Tyuleneva, L. A. Rozov, Yu. V. Zeifman & I. L. Knunyants

Authors
  1. V. V. Tyuleneva
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  2. L. A. Rozov
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  3. Yu. V. Zeifman
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  4. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1136–1139, May, 1975.

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Tyuleneva, V.V., Rozov, L.A., Zeifman, Y.V. et al. Exchange of fluorine by chlorine in perfluoroisobutylene. Russ Chem Bull 24, 1042–1045 (1975). https://doi.org/10.1007/BF00922961

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  • DOI: https://doi.org/10.1007/BF00922961

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