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Bromination of hydrocarbons by N-bromosuccinimide at high pressures

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The competing bromination of a number of hydrocarbons using N-bromosuceinimide at high pressures made it possible to establish that in reactions of the type Br + RH → Br ... H ... R → BrH + R the rule is retained, according to which the reactions that proceed most easily are accelerated most strongly by pressure.

  2. 2.

    The obtained rule is explained if we start with the concept of a variable elongation of the bonds in the formation of the transition state.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. M. Zhulin, M. Ya. Botnikov & I. Kh. Milyavskaya

Authors
  1. V. M. Zhulin
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  2. M. Ya. Botnikov
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  3. I. Kh. Milyavskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1131–1135, May, 1975.

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Zhulin, V.M., Botnikov, M.Y. & Milyavskaya, I.K. Bromination of hydrocarbons by N-bromosuccinimide at high pressures. Russ Chem Bull 24, 1038–1041 (1975). https://doi.org/10.1007/BF00922960

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  • DOI: https://doi.org/10.1007/BF00922960

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