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Dipole moments of adducts of pyridine and γ-picoline with derivatives of π-allylpalladium chloride

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The dipole moment ofπ-allyl complexes of palladium with the composition (RC3H4PdCl)2 and RC3H4PdCl (amine) were measured.

  2. 2.

    The moment of theπ-allyl-palladium bond is 2–2.5 D and is directed from the allyl to the Pd, i. e., the allyl group carries a positive charge in comparison with the metal atom.

  3. 3.

    The observed dipole moments of binuclear complexes agree with the assumption of a disruption of the planar character of the bridge Pd2Cl2 group in solution.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    O. G. Levanda, G. N. Kartsev, S. I. Ignat'eva & I. I. Moiseev

  2. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR

    O. G. Levanda, G. N. Kartsev, S. I. Ignat'eva & I. I. Moiseev

Authors
  1. O. G. Levanda
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  2. G. N. Kartsev
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  3. S. I. Ignat'eva
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  4. I. I. Moiseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1077–1081, May, 1975.

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Levanda, O.G., Kartsev, G.N., Ignat'eva, S.I. et al. Dipole moments of adducts of pyridine and γ-picoline with derivatives of π-allylpalladium chloride. Russ Chem Bull 24, 986–989 (1975). https://doi.org/10.1007/BF00922948

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  • DOI: https://doi.org/10.1007/BF00922948

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