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Influence of substituents of the conformation of molecules with two geminal C-SR bonds

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

1,1-Bis(arylthio)ethanes exist in solutions in the form of conformers with trans-gauche and trans-trans conformations of the C-S-C-S-C chain, while geminal disulfones based on them exist in transgauche and gauche-gauche conformations, with the radicals situated on different sides of the plane of S-C-S.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, I. I. Dapkin, A. P. Timosheva, E. A. Berdnikov, N. S. Zelenina & A. N. Vereshchagin

  2. Perm State University, USSR

    B. A. Arbuzov, I. I. Dapkin, A. P. Timosheva, E. A. Berdnikov, N. S. Zelenina & A. N. Vereshchagin

  3. V. I. Ul'yanov-Lenin Kazan' State University, USSR

    B. A. Arbuzov, I. I. Dapkin, A. P. Timosheva, E. A. Berdnikov, N. S. Zelenina & A. N. Vereshchagin

Authors
  1. B. A. Arbuzov
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  2. I. I. Dapkin
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  3. A. P. Timosheva
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  4. E. A. Berdnikov
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  5. N. S. Zelenina
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  6. A. N. Vereshchagin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1073–1077, May, 1975.

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Arbuzov, B.A., Dapkin, I.I., Timosheva, A.P. et al. Influence of substituents of the conformation of molecules with two geminal C-SR bonds. Russ Chem Bull 24, 982–985 (1975). https://doi.org/10.1007/BF00922947

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  • DOI: https://doi.org/10.1007/BF00922947

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