Conclusions
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1.
The photoelectronic spectra of a number of organophosphorus compounds of the type of WPXYZ were obtained and interpreted for the first time.
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2.
The upper orbital is primarily localized on the pπ-orbitals of the W atom, participates in the bonding of WP, and has little conjugation with the orbitals of the unshared pairs of the substituents. Exceptions are nitrogen-containing substituents.
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3.
Series of atoms W with respect to decreasing influence on the ionization potentials of the UEP of the substituents XYZ were established: for nonnitrogen-containing substituents OP > SP > P, and for nitrogen-containing substituents SP > OP > P.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1051–1057, May, 1975.
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Zverev, V.V., Vilesov, F.I., Vovna, V.I. et al. Photoelectronic spectra and intramolecular intractions in compounds of tetracoordinated phosphorus. Russ Chem Bull 24, 961–966 (1975). https://doi.org/10.1007/BF00922942
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DOI: https://doi.org/10.1007/BF00922942