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PMR spectra and steucture of esters of phosphonic acid

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The PMR spectra of a number of esters of phosphonic acids RP(O)(OEt)2 where R represents alkyl or substituted alkyl, were studied.

  2. 2.

    The influence of the substituents on the chemical shift of the proton of the PCH fragment and the conditions of its correlation with the induction constants of the substituents, as well as with the chemical shift of31P of this fragment, was considered.

  3. 3.

    The spin-spin interaction constants2JHP and1JCP in the PMR and NMR-13C spectra of phosphonates show a correlated variation.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch of the Academy of Sciences of the USSR, USSR

    V. E. Bel'skii, L. A. Kudryavtseva, A. M. Kurguzova & B. E. Ivanov

Authors
  1. V. E. Bel'skii
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  2. L. A. Kudryavtseva
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  3. A. M. Kurguzova
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  4. B. E. Ivanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1047–1051, May, 1975.

The authors would like to express their gratitude to T. A. Zyablikova and R. G. Gainullina for their measurement of the spectra.

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Bel'skii, V.E., Kudryavtseva, L.A., Kurguzova, A.M. et al. PMR spectra and steucture of esters of phosphonic acid. Russ Chem Bull 24, 958–960 (1975). https://doi.org/10.1007/BF00922941

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  • DOI: https://doi.org/10.1007/BF00922941

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