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Calculation of the kinetic parameters of reactions of proton transfer between cyanines and OH acids

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A theoretical investigation was made of the reactions of proton transfer between 2, 2′-cyanines and carboxylic acids. The kinetic parameters were calculated for this series. Good agreement of the theoretical results with the experimental data were shown.

  2. 2.

    From an analysis of the isotopic effect, the values of the valence and deformational frequencies of the C-H bond in cyanine were determined, and estimates of the distance of proton transfer were made.

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Authors and Affiliations

  1. Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow

    M. I. Gverdtsiteli, É. D. German & R. R. Dogonadze

  2. Tbilisi State University, USSR

    M. I. Gverdtsiteli, É. D. German & R. R. Dogonadze

Authors
  1. M. I. Gverdtsiteli
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  2. É. D. German
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  3. R. R. Dogonadze
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1029–1035, May, 1975.

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Gverdtsiteli, M.I., German, É.D. & Dogonadze, R.R. Calculation of the kinetic parameters of reactions of proton transfer between cyanines and OH acids. Russ Chem Bull 24, 942–947 (1975). https://doi.org/10.1007/BF00922938

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  • DOI: https://doi.org/10.1007/BF00922938

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