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Exchange of deuterium with hydrogen on the surface of zeolite catalyst

Communication 3. Divalent cationic forms of Y zeolites

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In type Y Mg-, Cd-, Zn-, Mn-, Ni-, and Co-zeolites there are at least two types of hydrogen, differing in rate of exchange with D2. In the zeolites CaY and SrY, protium is kinetically homogeneous in exchange with deuterium.

  2. 2.

    The concentrations and mobilities of various forms of hydrogen in the investigated zeolites were determined.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    R. V. Dmitriev, Ya. I. Isakov, N. Ya. Usachev, A. N. Detyuk & Kh. M. Minachev

Authors
  1. R. V. Dmitriev
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  2. Ya. I. Isakov
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  3. N. Ya. Usachev
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  4. A. N. Detyuk
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  5. Kh. M. Minachev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1011–1015, May, 1975.

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Dmitriev, R.V., Isakov, Y.I., Usachev, N.Y. et al. Exchange of deuterium with hydrogen on the surface of zeolite catalyst. Russ Chem Bull 24, 927–930 (1975). https://doi.org/10.1007/BF00922935

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  • DOI: https://doi.org/10.1007/BF00922935

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