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Characteristics of the chemical bond in CuCl 2−4 according to the esr data

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The expressions for the magnetic parameters of planoquadratic complexes with a d9 were refined.

  2. 2.

    The influence of the calculated approximations on the theoretical values of the magnetic parameters of the complex CuCl 2−4 was investigated.

  3. 3.

    A consideration of the states with charge transfer (together with spin-orbital interaction on the ligands) can also be important for compounds that do not exhibit anomalous values of the magnetic parameters.

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Authors and Affiliations

  1. Physicotechnical Institute, Kazan' Branch of the Academy of Sciences of the USSR, USSR

    V. P. Zentsov, I. V. Ovchinnikov & N. B. Yunusov

Authors
  1. V. P. Zentsov
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  2. I. V. Ovchinnikov
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  3. N. B. Yunusov
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Additional information

Translated from Izvestiya Akdemii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 994–997, May, 1975.

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Zentsov, V.P., Ovchinnikov, I.V. & Yunusov, N.B. Characteristics of the chemical bond in CuCl 2−4 according to the esr data. Russ Chem Bull 24, 908–910 (1975). https://doi.org/10.1007/BF00922930

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  • DOI: https://doi.org/10.1007/BF00922930

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