Conclusions
-
1.
Together with reactions H +RH=H2 + R, reactions H + R1H=R1H + H(A), where R1H is a free radical, occur with a rapid rate.
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2.
The consideration of reactions of type (A) is necessary in those cases when together with free H or D atoms are present molecules containing D or H atoms, separately or both isotopes together.
Literature cited
V. V. Azatyan and S. B. Filippov, Dokl. Akad. Nauk SSSR,184, 625 (1969).
M. K. Berlie and D. J. LeRoy, Disc. Faraday Soc.,14, 50 (1953).
H. J. Sniff, Disc. Faraday Soc.,14, 121 (1953).
H. A. Kazmi and D. J. LeRoy, Canad. J. Chem.,42, 1145 (1964).
K. H. Geib and E. W. R. Steacie, Z. Phys. Chem.,B-29, 215 (1935).
E. Gorin, W. Kuzmann, J. Walter, and H. Eyring, J. Chem. Phys.,7, 633 (1933).
S. Glasstone, K. Laidler, and H. Eyring, Theory of Absolute Reaction Rates [Russian translation], Izd. IL (1955).
V. V. Azatyan, A.B. Nalbandyan, and K. T. Oganesyan, Dokl. Akad. Nauk SSSR,157, 931 (1964).
Z. G. Dzotsenidze, K. T. Oganesyan, G. A. Sachyan, and A. B. Nalbandyan, Arm. Khim. Zh.,20, 983 (1967).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1186–1187, May, 1969.
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Azatyan, V.V., Filippov, S.B. A reaction of free hydrogen atoms with deuterium. Russ Chem Bull 18, 1093–1094 (1969). https://doi.org/10.1007/BF00922886
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DOI: https://doi.org/10.1007/BF00922886