Conclusions
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1.
The authors have studied the radiolysis of glucose in phosphoric acid solutions at 77°K by the EPR method.
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2.
The transition Rphos → Rglucose was detected during heating of irradiated specimens.
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3.
Like the formation of radicals from phosphoric acid, the formation of radicals from glucose at the temperature of liquid nitrogen may be due to capture of H2O+ by these molecules.
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Literature cited
P. N. Moorthy and J. J. Weiss, J. Chem. Phys.,42, 3127 (1965).
M. Miura, A. Hasegava, and T. Furui, Bull. Chem. Soc. Japan,39, 1432 (1966).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1183–1185, May, 1969.
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Sharpatyi, V.A., Sultankhodzhaeva, M.N. The role of positively charged paramagnetic particles in the radiolytic decomposition of glucose. Russ Chem Bull 18, 1088–1090 (1969). https://doi.org/10.1007/BF00922884
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DOI: https://doi.org/10.1007/BF00922884