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Reduction of the p-dimethylaminodiphenylferrocenyl and p-dimethylaminotriphenylmethyl cations

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When p-dimethylaminodiphenylferrocenylcarbonium tetraphenylborate is heated with dimethylaniline, reduction of the carbocation to p-dimethylaminodiphenylferrocenylmethane occurs.

  2. 2.

    The alkylation of dimethylaniline in the p-position takes place along with the reduction when p-dimethylaminotriphenylcarbonium tetraphenylborate is used.

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Literature cited

  1. A. N. Nesmeyanov, V. A. Sazonova, V. N. Drozd, N. A. Rodionova, and G. I. Zudkova, Izv. Akad. Nauk SSSR, Ser. Khim., 2061 (1965).

  2. A. N. Nesmeyanov, V. A. Sazonova, G. I. Zudkova, and L. S. Isaeva, Izv. Akad. Nauk SSSR, Ser. Khim., 2017 (1966).

  3. W. Bonthrone and D. H. Reid, J. Chem. Soc., 2773 (1959).

  4. A. N. Nesmeyanov, V. A. Sazonova, V. N. Drozd, and N. A. Rodionova, Dokl. Akad. Nauk SSSR,166, 355 (1964).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. N. Nesmeyanov, G. I. Zudkova & V. A. Sazonova

Authors
  1. A. N. Nesmeyanov
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  2. G. I. Zudkova
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  3. V. A. Sazonova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1171–1174, May, 1969.

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Nesmeyanov, A.N., Zudkova, G.I. & Sazonova, V.A. Reduction of the p-dimethylaminodiphenylferrocenyl and p-dimethylaminotriphenylmethyl cations. Russ Chem Bull 18, 1074–1076 (1969). https://doi.org/10.1007/BF00922878

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  • DOI: https://doi.org/10.1007/BF00922878

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