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α-Methyl-α-chloro-β-propiothiolactone in the synthesis of derivatives of thioglycidic acid

  • M. G. Lin'kova
  • A. M. Orlov
  • O. V. Kil'disheva
  • I. L. Knunyants
Organic and Biological Chemistry

Conclusions

  1. 1.

    The piperidide and the methyl ester ofα-methyl-α,β-thioglycidic acid have been prepared.

     
  2. 2.

    Amides ofα-methyl-α,β-thioglycidic acid are readily cleaved by chlorine to form preferentiallyβ-chloro-α-sulfenchlorides.

     
  3. 3.

    Besides having the usual properties of thiiranes, amides ofα-methyl-α,β-thioglycidic acid are characterized by the fact that under the influence of traces of piperidine they redistribute the sulfur to form amides of methacrylic acid and disulfides.

     

Keywords

Sulfur Methyl Ester Amide Chlorine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1969

Authors and Affiliations

  • M. G. Lin'kova
    • 1
  • A. M. Orlov
    • 1
  • O. V. Kil'disheva
    • 1
  • I. L. Knunyants
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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