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Addition reactions of linear siloxanes to allylamine

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reactions of pentamethyldisiloxane and sym-methylphenyldisiloxane with allylamine have been studied.

  2. 2.

    The reactions of linear siloxanes with allylamine lead to the formation of addition products containing an amino group in theγ-position in an organic radical attached to the silicon atom.

  3. 3.

    The structures of the compounds obtained have been confirmed by independent synthesis and by analysis of their IR absorption spectra and NMR spectra.

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Literature cited

  1. N. S. Nametkin, A. V. Topchiev, T. I. Chernysheva, and I. I. Lyashenko, Dokl. Akad. Nauk SSSR,140, 384 (1961).

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  2. S. N. Borisov, V. V. Vinogradova, I. N. Lyashenko, N. S. Nametkin, and T. I. Chernysheva, Izv. Akad. Nauk SSSR, Ser. Khim.,1964, 2230.

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  4. Handbook. Synthesis of Complex Compounds of Metals of the Pt Group [in Russian], Nauka (1964), p. 8.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, USSR

    I. N. Lyashenko, N. S. Nametkin & T. I. Chernysheva

Authors
  1. I. N. Lyashenko
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  2. N. S. Nametkin
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  3. T. I. Chernysheva
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Additional information

This paper is published on the basis of a resolution of a Conference of the Chief Editors of the Journals of the Academy of Sciences of the USSR of July 12, 1962, as the dissertation work of I. N. Lyashenko.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1132–1135, May, 1969.

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Lyashenko, I.N., Nametkin, N.S. & Chernysheva, T.I. Addition reactions of linear siloxanes to allylamine. Russ Chem Bull 18, 1034–1036 (1969). https://doi.org/10.1007/BF00922866

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  • DOI: https://doi.org/10.1007/BF00922866

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