Skip to main content
SpringerLink
Log in

Investigation of the formation of catalysts by the method of thermal chromatography

Communication 3. Zinc-chromium catalysts

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The formation of zinc-chromium catalysts with various chromic anhydride contents were studied by the method of thermal chromatography.

  2. 2.

    Zinc-chromium catalysts eliminate water in two steps during heating in inert medium, followed by step-wise decomposition of the series of zinc chromates formed during preparation to a spinel phase of zinc chromite. The content of nonstoichiometric oxygen was calculated.

  3. 3.

    The process of formation of zinc-chromium catalysts in a reducing medium consists of an easier and more profound step-wise elimination of oxygen; the spinel phase of zinc chromite is formed at a substantially lower temperature in reducing medium. Considering the results obtained, the literature data on the topochemical reactions that occur during processes of formation of zinc-chromium catalysts are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. E. Z. Golosman, V. I. Yakerson, A. M. Alekseev, and L. M. Il'icheva, Izv. AN SSSR, Ser. Khim, 837 (1969); E. Z. Golosman, V. I. Yakerson and L. M. Il'icheva, Izv. AN SSSR, Ser. Khim., 844 (1969).

  2. S. Beilas, Chemical Kinetics and Calculations of Industrial Reactors [Russian translation], Khimiya, Moscow-Leningrad (1967).

    Google Scholar 

  3. T. V. Rode, Oxygen Compounds of Chromium and Chromium Catalysts [in Russian], Izd-vo AN SSSR (1962).

  4. Scientific Bases of the Selection and Production of Catalysts [in Russian], Izd-vo AN SSSR, Novosibirsk (1967).

  5. D. B. Chistozvonov, The Nitrogen Industry [in Russian], ONTI, GIAP, (1965), p.46.

  6. G. Garko, Methods of Analytical Chemistry [Russian translation], Khimiya, Moscow-Leningrad (1965), p. 910.

    Google Scholar 

  7. A. M. Dymov, Theoretical Analysis of Ores and Minerals [in Russian], GNTI (1944), p. 171.

  8. Analysis of Mineral Raw Materials [in Russian], GNTI, Leningrad (1959), p. 387.

  9. K. P. Stolyarov and F. B. Agrest, Zh. Analiticheskoi Khim.,19, 457 (1967).

    Google Scholar 

  10. I. P. Kirillov, N. P. Opolovnikova and A. M. Alekseev, Catalysis and Catalysts [in Russian], Khimiya i Khim. Tekhnologii,7, 77 (1964).

    Google Scholar 

  11. Yu. M. Shutov, T. A. Semenova, F. F. Kravchenko, E. A. Boevskaya and R. P. Muganova, Tr. GIAP (1968), p. 107.

  12. V. M. Vlasenko, B. I. Kruglov, M. G. Rozenfel'd, and M. T. Rusov, Khim. Prom-st', No. 1, 1 (1962).

    Google Scholar 

  13. V. M. Vlasenko, Catalysis and Catalysts [in Russian], Izd. AN SSSR, Kiev (1965), p. 131.

    Google Scholar 

  14. V. M. Vlasenko, M. G. Rozenfel'd, and M. G. Rusov, Scientific Bases of the Selection and Production of Catalysts [in Russian], Izd-vo AN SSSR, Novosibirsk (1964), p. 160.

    Google Scholar 

  15. Ya. V. Zhigailo, L. I. Shpak, T. P. Gaibei, V. I. Duginskaya, and V. V. Taksha, Khim. Prom-st', No. 1, 29 (1963).

    Google Scholar 

  16. Ya. V. Zhigailo, Methods of Investigating Catalysts and Catalytic Reactions [in Russian], Izd-vo AN SSSR, Novosibirsk,2 (1965), p. 362.

    Google Scholar 

  17. Ya. V. Zhigailo, Scientific Bases of the Selection and Production of Catalysts [in Russian], Izd-vo AN SSSR, Novosibirsk (1967), p. 167.

    Google Scholar 

  18. T. A. Semenova, M. I. Markina, B. G. Lyudkovskaya, B. I. Shteinberg, L. I. Kozlov, and N. F. Khitrova, Methods of Investigating Catalysts and Catalytic Reactions [in Russian], Izd-vo AN SSSR, Novosibirsk,2 (1965), p. 346.

    Google Scholar 

  19. D. P. Ivanovskii, G. E. Braude, T.A. Semenova, and B. G. Lyudkovskaya, Problems of Kinetics and Catalysis [in Russian], Izd-vo AN SSSR (1960), p. 90.

  20. H. Uchida, M. Oba, and M. Araki, Bull. Chem. Soc. Japan, 38, 1993 (1965).

    Google Scholar 

  21. V. D. Livshits and B. G. Lyudkovskaya, Chemistry and Technology of Products of Organic Synthesis [in Russian], ONTI, GIAP (1967), p. 46.

  22. T. Grie and T. Shiraishi, J. Chem. Soc. Japan, Pure Chem. Soc.,80, 107 (1957).

    Google Scholar 

  23. N. P. Opolovnikova, A.M. Alekseev, and I. P. Kirillov, Izv. Vyssh. Uchebn. Zavedenii, Khimiya i Khim. Tekhnologii,8, 633 (1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    V. I. Yakerson, E. Z. Golosman & Yu. M. Shutov

  2. Novomoskovsk Branch of the State Scientific Research and Planning Institute of the Nitrogen Industry and Products of Organic Synthesis, USSR

    V. I. Yakerson, E. Z. Golosman & Yu. M. Shutov

Authors
  1. V. I. Yakerson
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Z. Golosman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. M. Shutov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.5, pp. 1065–1072, May, 1969.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yakerson, V.I., Golosman, E.Z. & Shutov, Y.M. Investigation of the formation of catalysts by the method of thermal chromatography. Russ Chem Bull 18, 973–978 (1969). https://doi.org/10.1007/BF00922852

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00922852

Keywords

Search

Navigation