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Investigation of the nuclear quadrupole resonance spectra of etherates of polyhalides of elements of group IVB

  • T. A. Babushkina
  • S. P. Kolesnikov
  • O. M. Nefedov
  • V. I. Svergun
  • G. K. Semin
Physical Chemistry
  • 16 Downloads

Conclusions

  1. 1.

    The NQR spectra of Cl35 in etherates of di-, tri-, and tetrachlorides of elements of group IVB were studied.

     
  2. 2.

    Trichlorogermane etherate 2(C2H5)2O·HGeCl3 (just like the etherate oftetrachlorostannane 2(C2H5)2O ·SnCl4) has a donor-acceptor nature and is characterized by a change in the coordination number of the central atom, nonequivalence of the chlorine atoms, and an increase in the degree of ionic character of the Ge-Cl(Sn-Cl) bonds.

     

Keywords

Chlorine Coordination Number Tetrachloride Chlorine Atom SnCl4 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    S. P. Kolesnikov, T. A. Babushkina, V. I. Sheichenko, G. S. Semin, and O. M. Nefedov, Summaries of Reports at the Second All-Union Conference on the Investigation of the Structure and Reactivity of Organic Substances by Physical Methods [in Russian], Izd-vo Ilim (1966), p. 266.Google Scholar
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    O.M. Nefedov, S. P. Kolesnikov, V. I. Sheichenko, and Yu. N. Sheinker, Dokl. Akad. Nauk SSSR,162, 589 (1965).Google Scholar
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    O. M. Nefedov and S. P. Kolesnikov,-Izv. Akad. Nauk SSSR, Ser. Khim., 201 (1966).Google Scholar
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    J. D. Graybeal and M. H. Hsu, Bull. Amer. Phys. Soc.,12, 468 (1967).Google Scholar

Copyright information

© Consultants Bureau 1969

Authors and Affiliations

  • T. A. Babushkina
    • 1
    • 2
  • S. P. Kolesnikov
    • 1
    • 2
  • O. M. Nefedov
    • 1
    • 2
  • V. I. Svergun
    • 1
    • 2
  • G. K. Semin
    • 1
    • 2
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR
  2. 2.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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