Conclusions
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1.
The ionization constants of 1,1-dinitroethane, nitroacetic and nitropropionic esters, 1- and 2-nitropropanes, nitroethane, and nitromethane were determined in methanol at 25°.
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2.
A linear relationship was found between the reciprocal logarithms of the dissociation constants of nitro-compounds in water and methanol.
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3.
The presence of a bathochromic shift of the absorption maxima of mononitroalkane anions in the UV region upon a change from water to methanol was demonstrated.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1039–1046, May, 1969.
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Belokon', Y.N., Faleev, N.G. & Belikov, V.M. Dissociation constants of certain nitro-compounds and UV spectra of their anions in methanol. Russ Chem Bull 18, 949–955 (1969). https://doi.org/10.1007/BF00922847
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DOI: https://doi.org/10.1007/BF00922847