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Reaction of thiodiacetone alcohol with chlorides of trivalent phosphorus acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Thiodiacetone alcohol reacts with the monochlorides of trivalent phosphorus acids in the presence of a base to give tricoordinated phosphorus derivatives. 2-Ethoxy-2-thio-3,5,5-trimethyl-1,2-thia-3-phos-pholanol is formed in the case of ethyl dichlorophosphite.

  2. 2.

    The reaction of thiodiacetone alcohol with phenyldichlorophosphine in the absence of a base gives 2-phenyl-2-thio-1,2-oxa-3,3,5-trimethyl-4-phospholene.

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Literature cited

  1. N. I. Rizpolozhenskii and F. S. Mukhametov, Izv. Akad. Nauk SSSR, Ser. Khim., 2755 (1968).

  2. N. I. Rizpolozhenskii and F. S. Mukhametov, Chemistry and Application of Organophosphorus Compounds [in Russian], Nauka (1972), p. 123.

  3. N. I. Rizpolozhenskii, F. S. Mukhametov, and R. R. Shagidullin, Izv. Akad. Nauk SSSR, Ser. Khim., 1121 (1969).

  4. B. A. Arbuzov, N. I. Rizpolozhenskii, A. O. Vizel, K. M. Ivanovskaya, F. S. Mukhametov, and É. M. Gol'dfarb, ibid., 117 (1971).

  5. N. I. Rizpolozhenskii, V. D. Akamsin, R. M. Eliseenkova, and R. R. Shagidullin, ibid., 2765 (1972).

  6. F. M. Rapoport and A. A. Il'inskaya, Laboratory Methods for the Preparation of Pure Gases [in Russian], Goskhimizdat (1963), p. 155.

  7. L. Föld and J. Kollonitsch, J. Chem. Soc., 1683 (1948).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    N. I. Rizpolozhenskii, L. V. Stepashkina & R. M. Eliseenkova

Authors
  1. N. I. Rizpolozhenskii
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  2. L. V. Stepashkina
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  3. R. M. Eliseenkova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2121–2124, September, 1974.

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Rizpolozhenskii, N.I., Stepashkina, L.V. & Eliseenkova, R.M. Reaction of thiodiacetone alcohol with chlorides of trivalent phosphorus acids. Russ Chem Bull 23, 2039–2041 (1974). https://doi.org/10.1007/BF00922817

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  • DOI: https://doi.org/10.1007/BF00922817

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