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Vibrational spectra of π-allyl complexes of rhodium

  • T. B. Chenskaya
  • L. A. Leites
  • V. T. Aleksanyan
  • A. S. Ivanov
  • A. Z. Rubezhov
Physical Chemistry

Conclusions

  1. 1.

    The IR and Raman spectra of tris-π-allylrhodium and bis-π-allylrhodium halides were studied. An assignment of the vibration frequencies was performed.

     
  2. 2.

    On the basis of an analysis of the effective selection rules, it was shown that all three π-allyl groups in (π-C3H5)3Rh, from the standpoint of vibrational spectroscopy, are equivalent, since the vibrations of the skeleton of the molecule obey C3h symmetry.

     
  3. 3.

    The redistribution of electron density in the “asymmetrical” π-allyl groups in bis-π-allylrhodium halides is inconsequential, since it is not manifested in the vibrational spectra.

     

Keywords

Spectroscopy Raman Spectrum Halide Rhodium Vibration Frequency 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    L. A. Leites, V. T. Aleksanyan, S. S. Bukalov, and A. Z. Rubezhov, Summaries of Reports at the Fifth International Congress on Organometallic Chemistry [in Russian], Vol. 3, VINITI, Moscow (1971), p. 302.Google Scholar
  2. 2.
    L. A. Leites, V. T. Aleksanyan, S. S. Bukalov, and A. Z. Rubezhov, Chem. Commun., 265 (1971).Google Scholar
  3. 3.
    L. A. Leites, V. T. Aleksanyan, and T. B. Chenskaya, Dokl. Akad. Nauk SSSR,215, 634 (1974).Google Scholar
  4. 4.
    T. B. Chenskaya, L. A. Leites, V. T. Aleksanyan, L. S. Isaeva, and L. I. Lorens, Zh. Strukt. Khim.,15, 31 (1974).Google Scholar
  5. 5.
    J. Powell and B. L. Shaw, Chem. Commun., 323 (1966).Google Scholar
  6. 6.
    A. Z. Rubezhov, A. S. Ivanov, and S. P. Gubin, Izv. Akad. Nauk SSSR, Ser. Khim., 951 (1973).Google Scholar
  7. 7.
    J. Powell and B. L. Shaw, J. Chem. Soc., A, 583 (1968).Google Scholar
  8. 8.
    J. K. Becconsall and S. O'Brien, Chem. Commun., 720 (1966).Google Scholar
  9. 9.
    D. C. Andrews and G. Davidson, J. Organometal. Chem., 383 (1973).Google Scholar
  10. 10.
    G. Wilke, B. Bogdanovic, P. Hardt, P. Heimbach, W. Keim, M. Kröner, W. Oberkirch, and K. Tanaka, Angew. Chem. Internat. Ed.,5, 151 (1966).Google Scholar
  11. 11.
    M. McPartlin and R. Mason, Chem. Commun., 16 (1967).Google Scholar
  12. 12.
    B. V. Lokshin, Z. S. Klemenkova, and Yu. V. Makarov, Spectrochim. Acta,28, 2209 (1972).Google Scholar
  13. 13.
    A. N. Nesmeyanov, O. V. Nogina, V. A. Dubovitskii, and B. V. Lokshin, Dokl. Akad. Nauk SSSR,182, 844 (1963).Google Scholar
  14. 14.
    G. Davidson, Organometal. Chem. Rev.,A8, 303 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • T. B. Chenskaya
    • 1
  • L. A. Leites
    • 1
  • V. T. Aleksanyan
    • 1
  • A. S. Ivanov
    • 1
  • A. Z. Rubezhov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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