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Molecular and electronic structure of heteropoly complexes

Communication 3.31P-NMR and x-ray electronic spectra of heteropoly compounds of phosphorus
  • L. P. Kazanskii
  • V. F. Chuvaev
  • V. N. Spitsyn
Inorganic Chemistry
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Conclusions

  1. 1.

    The31P-NMR spectra were measured in various heteropolycompounds and their solutions. The structure of the anion in aqueous solution is preserved.

     
  2. 2.

    The energies of the 2p-electrons of phosphorus in heteropolycompounds were measured and correlated with the31P-NMR chemical shifts.

     
  3. 3.

    The charge on the phosphorus atom increases in the series: PO 4 3− <PV12O 36 7− <PMo12O 40 3− <P2W17O 61 10− < PW11O 39 7− < PW12O 40 3− .

     

Keywords

Aqueous Solution Phosphorus Chemical Shift Phosphorus Atom Atom Increase 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • L. P. Kazanskii
    • 1
  • V. F. Chuvaev
    • 1
  • V. N. Spitsyn
    • 1
  1. 1.Institute of Physical ChemistryAcademy of Sciences of the USSRMoscow

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