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New fluorine-containing ethers

  • K. N. Makarov
  • T. N. Abroskina
  • Yu. A. Cheburkov
  • I. L. Knunyants
Brief Communications
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Conclusions

  1. 1.

    The cesium chloride adducts with perfluoroacetone, 1-methyl-2-oxaperfluoroenanthyl fluoride, and perfluoroisobutylene react smoothly with symmetrical dichlorodimethyl ether, replacing both chlorine atoms, with the formation of the corresponding ethers.

     
  2. 2.

    The interaction ofα,α-dihydroperfluoroamyl alcoholate with symmetrical dichlorodimethyl ether leads to the replacement of both chlorine atoms, with the formation of the corresponding ether.

     
  3. 3.

    The reaction of perfluoro-t-butylanion with tris(chloromethyl)amine leads to tris-(1,1-dihydro-perfluoroneopentyl) amine.

     
  4. 4.

    Perfluoro-t-butylanion replaces only one chlorine atom in the molecule of unsymmetrical di-chlorodimethyl ether, formingα-chloro-α -perfluoro-t-butyldimethyl ether.

     

Keywords

Ether Chloride Fluoride Chlorine Adduct 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • K. N. Makarov
    • 1
  • T. N. Abroskina
    • 1
  • Yu. A. Cheburkov
    • 1
  • I. L. Knunyants
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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