Reactions of perfluorovinyl ethers under the action of fluorine ions

  • A. A. Glazkov
  • A. V. Ignatenko
  • S. P. Krukovskii
  • V. A. Ponomarenko
Brief Communications
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Conclusions

  1. 1.

    The transformations of perfluoromethylvinyl and perfluoromethoxypropylvinyl ethers in the presence of ionic fluorides in aprotonic solutions have been studied.

     
  2. 2.

    In the absence of perfluoroolefins, prefluorovinyl ethers do not form dimers with unsaturated bonds, but are transformed into perfluoroetheroketones as the result of a series of successive reactions.

     

Keywords

Ether Fluoride Fluorine Successive Reaction Ionic Fluoride 

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Literature cited

  1. 1.
    T. A. Mashburn, U. S. Patent 3257466 (1966); Chem. Abstr.65, 13544 (1966).Google Scholar
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    D. P. Graham, J. Org. Chem.31, 955 (1966).Google Scholar
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    F. S. Fawcett, C. W. Tullock, and D. D. Coffman, J. Am. Chem. Soc.,84, 4275 (1962).Google Scholar
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    R. D. Smith, F. S. Fawcett, and D. D. Coffman, J. Am. Chem. Soc.,84, 4285 (1962).Google Scholar
  5. 5.
    P. R. Reznik, Fifth International Symposium on the Chemistry of Fluorine, Abstracts of Proceedings [in Russian], Nauka, 1969, p. 6.Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • A. A. Glazkov
    • 1
  • A. V. Ignatenko
    • 1
  • S. P. Krukovskii
    • 1
  • V. A. Ponomarenko
    • 1
  1. 1.N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSRMoscow

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