Conclusions
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1.
Tetrafluorodibromomethane inhibits the combustion of carbon monoxide, taking place in the presence of traces of hydrogen-containing compounds.
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2.
The rate constant of the reaction between atoms of hydrogen and tetrafluorobromomethane has been determined from data on the inhibition of the ignition of carbon monoxide at 650°.
Literature cited
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V. V. Azatyan, V. V. Voevodskii, and A. B. Nalbandyan, Kinet. Katal.,2, 341 (1961).
V. V. Azatyan, Arm. Khim. Zh.,20, 577 (1967).
V. N. Kondrat'ev, Rate Constants of Gas-Phase Reactions [in Russian], Izd. Nauka (1970).
N. I. Parsamyan, L. D. Petrova, V. V. Azatyan, L. P. Vogman, and A. N. Baratov, Proceedings of Third All-Union Conference on Combustion and Extinction [in Russian], Izd. VNIIPO MVD SSSR, Moscow (1973).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya Nauk, No. 4, pp. 905–907, April, 1976.
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Petrova, L.D., Azatyan, V.V. & Baratov, A.N. Study of ignition of carbon monoxide with additions of halogen hydrocarbons near the first ignition limit. Russ Chem Bull 25, 882–884 (1976). https://doi.org/10.1007/BF00922403
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DOI: https://doi.org/10.1007/BF00922403