Conclusions
-
1.
The influence of sym. C2F4Br2 and CF2Br on the spontaneous combustion of hydrogen near the first and the second inflammability limits has been studied.
-
2.
The rate constants of the reaction of H atoms with sym. C2F4Br2 in the range 600–680°, as well as the rate constant of the reaction of H atoms with CF3Br have been determined. These reactions are the primary stages of inhibition.
Literature cited
A. N. Baratov and L. D. Petrova, in: Inhibition of Gas Chain Reactions [in Russian], Izd-voKazakh. Univers., Alma-Ata (1971).
I. M. Abduragimov, in: The Third All-Union Symposium on Combustion [in Russian], Nauka, Leningrad (1971).
V. V. Azatyan and M. A. Namoradze, The Physics of Combustion and Explosion [in Russian] (1973), p. 93.
V. V. Azatyan, Kinet. Katal.,16, 567 (1975).
V. V. Azatyan, Arm. Khim. Zh.,20, 577 (1967).
N. N. Semenov, Problems of Chemical Kinetics and Reactivity [in Russian], Izd-vo Akad, Nauk SSSR (1958).
V. V. Azatyan, V. V. Voevodskii, and A. B. Nalbandyan, Kinetika i Kataliz,2, 340 (1971).
V. N. Kondrat'ev, Rate Constants of Gas Phase Reactions [in Russian], Nauka (1970).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 901–905, April, 1976.
Rights and permissions
About this article
Cite this article
Petrova, L.D., Azatyan, V.V., Baratov, A.N. et al. Reaction kinetics of hydrogen atoms with trifluorobromomethane and tetrafluorodibromoethane. Russ Chem Bull 25, 879–881 (1976). https://doi.org/10.1007/BF00922402
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00922402