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Unusual cleavage of adducts of trialkyl phosphites with perfluoromethacrylic acid derivatives

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Perfluoromethaerylic acid derivatives when reacted with trialkyl phosphites give stable adducts that contain a pentacoordinated phosphorus atom, and specifically are substitutedα-fluorovinyltrialkoxy-fluorophosphoranes.

  2. 2.

    The phosphoranes obtained from perfluoromethacrylic acid esters and trialkyl phosphites are cleaved when heated, in which connection the products of the Arbuzov reaction are not formed, but instead alkyl difluorophosphites and the esters ofα-trifluoromethyl-β,β-dialkoxyacrylic acids.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    I. L. Knunyants, U. Utebaev, E. M. Rokhlin, É. P. Lur'e & E. I. Mysov

Authors
  1. I. L. Knunyants
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  2. U. Utebaev
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  3. E. M. Rokhlin
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  4. É. P. Lur'e
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  5. E. I. Mysov
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Additional information

See [1] for preliminary communication.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 875–882, April, 1976.

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Knunyants, I.L., Utebaev, U., Rokhlin, E.M. et al. Unusual cleavage of adducts of trialkyl phosphites with perfluoromethacrylic acid derivatives. Russ Chem Bull 25, 853–860 (1976). https://doi.org/10.1007/BF00922396

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  • DOI: https://doi.org/10.1007/BF00922396

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