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The hydroalumination reaction for some alkenyltrimethylsilanes with diisobutylaluminum hydride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The disubstituted double bond in theβ-position with respect to the silicon atom does not enter into the hydroalumination reaction because of the interaction of theπ-electrons with the 3d-vacant orbitale of the silicon atom.

  2. 2.

    The disubstituted double bond, which is removed from the silicon atom, enters into the hydro-alumination reaction without a shift in the vinyl position to form organoaluminum compounds which contain the silicon atom.

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Authors and Affiliations

  1. Institute of Chemistry of the Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    V. P. Yur'ev, G. A. Gailyunas, F. G. Yusupova, G. A. Tolstikov & I. Kh. Aminev

Authors
  1. V. P. Yur'ev
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  2. G. A. Gailyunas
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  3. F. G. Yusupova
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  4. G. A. Tolstikov
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  5. I. Kh. Aminev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 866–869, April, 1976.

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Yur'ev, V.P., Gailyunas, G.A., Yusupova, F.G. et al. The hydroalumination reaction for some alkenyltrimethylsilanes with diisobutylaluminum hydride. Russ Chem Bull 25, 844–847 (1976). https://doi.org/10.1007/BF00922394

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  • DOI: https://doi.org/10.1007/BF00922394

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