Conclusions
-
1.
Telomer homologs of the type CCl3(CH2CDCl)nX, where n=1−3 and X=H, Cl or Br, have been synthesized.
-
2.
The structure of the telomerization products has been demonstrated by PMR spectroscopy, and the different diasstereomeric racemic pairs have been identified for compounds with two or three chiral centers.
Similar content being viewed by others
Literature cited
T. A. Onishchenko, Dissertation, Moscow (1971).
B. A. Englin, T. A. Onishchenko, V. A. Valovoi, T. A. Babushkina, G. K. Semin, L. G. Zelenskaya, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 332 (1969).
B. A. Englin, B. N. Osipov, V. A. Valovoi, T. A. Babushkina, G. K. Semin, V. B. Bondarev, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1251 (1968).
J. A. Pople, W. G. Schneider, and H. J. Bernstein, High Resolution Nuclear Magnetic Resonance, McGraw-Hill, New York (1959).
B. A. Englin, T. A. Onishchenko, Yu. V. Belov, V. I. Dostovalova, I. K. Shmyrev, and U. Utebaev, Izv. Akad. Nauk SSSR, Ser. Khim., 982 (1973).
B. A. Englin, Yu. V. Belov, A. E. Zolotarev, T. A. Onishchenko, I. K. Shmyrev, and R. Kh. Freidlina, Dokl. Akad Nauk SSSR,210, 880 (1973).
B. A. Englin, N. A. Grigor'ev, A. E. Zolotarev, V. I. Dostovalova, I. K. Shmyrev, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2216 (1973).
L. C. Leiten and A. T. Morse, Can. J. Chem.,30, 924 (1952); J. E. Frencis and L. C. Leitch, Can. J. Chem.,35, 500 (1957); T. Joshino and J. Komiyama, J. Polym. Sci.,B3, 311 (1965).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 845–849, April, 1976.
Rights and permissions
About this article
Cite this article
Onishchenko, T.A. PMR investigation of the structure of the telomerization products of α-d1-vinyl chloride with polyhalomethanes. Russ Chem Bull 25, 824–828 (1976). https://doi.org/10.1007/BF00922389
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00922389