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Electron exchange between aromatic nitro compounds and their anion radicals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate of the electron exchange between o-nitrochlorobenzene and its anion radical is significantly smaller than that expected from the correlation between logkexc anda N obtained for the meta- and para-substituted nitrobenzene.

  2. 2.

    The study of the spin-spin exchange in the anion radicals showed that the degree of overlap between the orbitals has no effect on electron exchange in the series of substituted nitrobenzenes.

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Literature cited

  1. N. M. Katkova, I. I. Bil'kis, and S. M. Shein, Kinet. Katal.,15, 1138 (1974).

    Google Scholar 

  2. N. M. Katkova and S. M. Shein, Kinet. Katal.,13, 492 (1972).

    Google Scholar 

  3. G. I. Skubnevskaya and Yu. N. Molin, Kinet. Katal.,8, 1192 (1967).

    Google Scholar 

  4. P. Ludvig, T. Layloff, and R. N. Adams, J. Amer. Chem. Soc.,86, 4568 (1964).

    Google Scholar 

  5. P. H. Rieger and G. K. Fraenkel, J. Chem. Phys.,39, 609 (1963).

    Google Scholar 

  6. P. A. Malachesky, T. A. Miller, T. Layloff, and R. N. Adams, Exchange Reaction, International Atomic Energy Agency (1965), p. 157.

  7. T. A. Miller and R. N. Adams, J. Amer. Chem. Soc.,88, 5713 (1966).

    Google Scholar 

  8. L. S. Degtyarev, A. M. Golubenkova, and A. I. Brodskii, Dokl. Akad. Nauk SSSR,191, 138 (1970).

    Google Scholar 

  9. A. Marcus, J. Chem. Phys.,43, 3477 (1965).

    Google Scholar 

  10. N. M. Katkova, V. S. Vainer, V. V. Brovko, S. M. Shein, and Yu. N. Molin, Kinet. Katal.,9, 64 (1970).

    Google Scholar 

  11. R. G. Parrich, G. S. Hall, and W. M. Gulick. Mol. Phys.,26, 1121 (1973).

    Google Scholar 

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Authors and Affiliations

  1. Siberian Branch, Novosibirsk Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    N. M. Katkova, I. I. Bil'kis & S. M. Shein

Authors
  1. N. M. Katkova
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  2. I. I. Bil'kis
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  3. S. M. Shein
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 771–774, April, 1976.

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Katkova, N.M., Bil'kis, I.I. & Shein, S.M. Electron exchange between aromatic nitro compounds and their anion radicals. Russ Chem Bull 25, 751–754 (1976). https://doi.org/10.1007/BF00922373

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  • DOI: https://doi.org/10.1007/BF00922373

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