Catalytic and magnetic properties of iron ε-nitride and carbonitride in reactions of dehydrogenation and amination of alcohols

  • R. A. Fridman
  • G. A. Kliger
  • E. I. Bogolepova
  • Yu. V. Maksimov
  • I. P. Suzdalev
Physical Chemistry

Conclusions

  1. 1.

    The catalytic properties of iron nitride (Fe2N) and carbonitride (Fe2C0.29N0.71) in the reactions of amination and dehydrogenation of alcohols were compared.

     
  2. 2.

    In the course of the amination and dehydrogenation reactions on a nitride catalyst, there is an “elution” of part of the introduced nitrogen from the surface with the formation of the structure of the lower nitride.

     
  3. 3.

    For related structures of the nitride and carbonitride, a correlation was detected between the catalytic activity and the average magnetic moment of the iron atom in the alloy.

     

Keywords

Nitrogen Iron Alcohol Catalytic Activity Magnetic Property 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • R. A. Fridman
    • 1
    • 2
  • G. A. Kliger
    • 1
    • 2
  • E. I. Bogolepova
    • 1
    • 2
  • Yu. V. Maksimov
    • 1
    • 2
  • I. P. Suzdalev
    • 1
    • 2
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow
  2. 2.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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